I think would look great. Red is one of few colors that pulls off a black rim really well. Here is a link to paint a set of salad shooters.
http://www.cardomain.com/ride/2357346/3
I painted mine the exact way and I rocked them last winter when I had my chrome ten spokes. They lasted all winter and still look great, Wet sanding each coat was key for a nice shine but if you want a satin look then i wouldn't worry about it. GL and get some pics when its done.